US EPA Translators
using Default Partition Coefficients (DPC)
v. 6/2/2010
Translator equation using Default Partition Coefficients = 1
[1 + (Kpo * TSS (1+a) * 10-6)]
Kpo and a are constants that express the equilibrium relationship between dissolved and adsorbed forms of metals.
A default value of 10 mg/L of Total Suspended Solids (TSS) will be used.
Table A contains the Default Partition Coefficients for the equation.
Table B contains the calculated translators using the default partition coefficients for streams.
TABLE A. Default Partition Coefficients
| |
FRESH WATER STREAMS |
| Metal (1) |
Kpo |
a |
| Cu |
1.04E+06 |
-0.7436 |
| Zn |
1.25E+06 |
-0.7038 |
| Pb |
2.80E+06 |
-0.8 |
| Cr (III) (2) |
3.36E+06 |
-.09304 |
| Cd |
4.00E+06 |
-1.1307 |
| Ni |
4.90E+05 |
-0.5719 |
(1) Delos, C.G., et al. Technical Guidance for Performing Waste Load Allocations. Book II: Streams and Rivers. Chapter 3: Toxic Substances, For the U.S. EPA. (EPA-440/4-84-022)
(2) Linear partition coefficients shall not apply to the Chromium VI numerical criterion. The approved analytical method for Chromium VI measures only the dissolved form. Therefore, permit limits for Chromium VI shall be expressed in the dissolved form. See 40 CFR § 122.45(c)(3).
TABLE B. US EPA Translators
| PARAMETER |
US EPA Translators
Using stream Default Partition Coefficients
TSS = 10 mg/L
|
| Cadmium |
0.252 |
| Chromium III |
0.202 |
| Chromium VI |
1.000 |
| Chromium, Total |
N/A |
| Copper |
0.348 |
| Lead |
0.184 |
| Nickel |
0.432 |
| Silver |
1.000 |
| Zinc |
0.288 |
Example for Cadmium (streams)
Given:
TSS = 10 mg/L
Kpo = 4.00E + 06
a = -1.1307 |
Translator = 1 _
[1 + (Kpo * TSS (1+a) * 10-6)]
= ___ 1
[1 + (4.00x106 * 101-1.1307) * 10-6)]
= _ __ 1
[1+2.960465]
= 0.252 |